Overview
- Exempt for PV-modules
- no regulation on module waste
- no obligation for user to return modules
- no obligation for producer to take back modules
1. Module Power:
- 22 GW total installations in Germany
- 27 GW world wide production 2010
2. Integrated Module Waste:
- 60 GW integrated production
- 2 600 000 t integrated module waste
3. Toxic Materials:
- c-Si modules >1000 t Pb
- CdTe modules ≈ 560 t CdTe
4. Leaching Studies (from literature):
Cd and Pb leach out at rain water conditions.
1. Market Numbers
Installed PV-Power in Germany
World Production: PV-Modules
World Production: PV-Modules
2. Waste
Distributed Modules
Expected Waste of PV-Modules
3. Toxic Materials
Crystalline Silicon
CdS/CdTe
CdS/CIGS
WEEE and RoHS
WEEE = „Waste Electrical and Electronic Equipment“ Directive (2002/96/EG)
- Exempt for PV-modules
- no regulation on module waste
- no obligation for user to return modules
- no obligation for producer to take back modules
RoHS = „Restriction of Hazardous Substances“ Directive (2002/95/EG)
- Exempt for PV-modules
- RoHS-limits:
- 0.1 % for Pb
36 Pb in solder on Cu-ribbons of c-Si modules!! - 0.01 % for Cd
50 % Cd in CdTe and CdS!!
Produced Pollutants
4. Leaching Studies
Leaching Data from Literature
Leaching in Water Solutions
Conclusions
1. PV-ModulesexemptfromWEEEandRoHS in Europe.
2. Toxicmaterialsdistributedoverlargeareas:
c-Si modules > 1000 t Pb
CdTe modules ≈ 560 t CdTe
3. CdandPbleachoutfrommodulepiecesat close to rain water conditions.
4. AvoidCdandPb,makePVreally green
J. H. Werner, R. Zapf-Gottwick, L. Hamann
Institute for Photovoltaics
M. Koch and K. Fischer
Institute for Sanitary Engineering, Water Quality, and Solid Waste Management
University of Stuttgart, November 30, 2011